FOULING & CORROSION
SulfGen™ – Smart Chemistry for Cleaner Boilers
SulfGen™ enhances boiler reliability by preventing sticky deposits and corrosion at the source. Through targeted sulfation, it delivers cleaner surfaces, easier maintenance, and longer equipment life—especially in high-chlorine WtE operations.
THE CHALLENGE – CHLORINE INDUCED CORROSION
Tackling a Core Problem in WtE operation
Chlorine-containing fuels in Waste-to-Energy plants generate alkali chlorides in the flue gas, which condense on boiler surfaces, causing highly adhesive fly ash, low-melting-point deposits, and severe tube corrosion. Traditional mitigation through waste chemistry offers limited, slow-acting protection. As boilers run hotter and cleaner requirements tighten, this issue becomes increasingly critical for plant uptime and longevity.
CHEMISTRY THAT CHANGES OUTCOMES
From Sticky Chlorides to Brush-Off Sulfates
In standard operation, sulfur from the waste leads to limited SO₂-driven sulfation – too slow to prevent aggressive chloride deposition. SulfGen™ instead generates SO₃ through targeted injection, initiating fast, complete sulfation of chlorides on particles and surfaces. Operators report deposit transformation: what once needed mechanical cleaning can now be wiped off manually during outages.
Process | Reactant Sulfation Source | Sulfation Speed | Chloride Conversion | Result |
No sulfation generator | Sulfur may be available in waste in reactive form (SO₂) | Sulfur may be available in waste in reactive form (SO₂) May happen partially but is uncontrolled, not efficient and slow | Partial | Sticky, corrosive deposits |
SulfGen™ | Sulfur injected via secondary air generates the active SO₃ | Will happen fast and with greater effect | High | Dry, brittle, brushable ash |
PROVEN IN OPERATION
Tested, Proven, In Use for more 5 Years
SulfGen™ was developed by Joerg Krueger at the Klingele WtE plant in Weener, Germany. In full-scale operation for over five years using SRF (Secondary Recovered Fuel), the system has consistently delivered lower corrosion rates, reduced outage durations, and cleaner heat-transfer surfaces. Its field-proven reliability is a key reason SulfGen™ is gaining adoption in plants with high-chlorine or high-metal content fuels.
OPERATIONAL BENEFITS
THE SULFGEN SOLUTION
Fast Sulfation Where It Matters Most
SulfGen™ introduces a sulfur-based reactant via the secondary air nozzles, directly into the high-temperature combustion zone. This enables rapid in-situ conversion of alkali chlorides into stable sulfates, which have higher melting points and significantly lower adhesion. The result is a dramatic reduction in both fouling and corrosion potential, with no disruption to combustion or air staging.
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